Journal
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 13, Issue 33, Pages 15182-15188Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cp21089k
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Funding
- Consolider-Ingenio in Molecular Nanoscience of the Spanish MICINN/FEDER [CTQ2010-14892, CSD2007-0010]
- EC [FP7/2007-2013, 228334, 212025]
- French Programme Triangle de la Physique
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In this contribution we present new experimental and theoretical results for the intramolecular charge transfer (ICT) reaction underlying the dual fluorescence of 4-(dimethylamino) benzonitrile ( DMABN), which indicate that the fully twisted ICT (TICT) state is responsible for the time-resolved transient absorption spectrum while a distinct partially twisted ICT (pTICT) structure is suggested for the fluorescent ICT state.
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