4.6 Article

Photoionization of a protein isolated in vacuo

Journal

PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 13, Issue 34, Pages 15432-15436

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cp21211g

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Funding

  1. Agence Nationale de la Recherche Scientifique, France [BLAN08-1_348053]
  2. COST Action [CM0601]
  3. Electron Controlled Chemical Lithography (ECCL)
  4. Ministry of Science and Technological Development of Republic of Serbia [141011]
  5. SOLEIL [20090295]

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Gas phase VUV single-photon photoionization spectroscopy of electrospray-produced multiply protonated cytochrome c protein ( 12 kDa) has been performed by means of coupling a linear quadrupole ion trap with a synchrotron beamline. The thresholds for the ionization of the 8+ and 11+ charge state precursors to radical 9+ and 12+ species were measured to be 12.75 +/- 0.10 and 13.51 +/- 0.10 eV, respectively.

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