Journal
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 13, Issue 26, Pages 12277-12284Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c0cp02553d
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Funding
- JSPS [22656155]
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Desorption of thiolate self-assembled monolayers (SAMs) seriously limits the fabrication of thiol-based devices. Here we demonstrate that nanoporous Au produced by dealloying Au-Ag alloys exhibits high electrochemical stability against thiolate desorption. Nanoporous Au has many defective sites, lattice strain and residual Ag on the ligament surface. First-principles calculations indicate that these surface aspects increase the binding energy between a SAM and the surface of nanoporous Au.
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