Journal
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 13, Issue 16, Pages 7467-7474Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c1cp20164f
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Funding
- CSC (Chinese Scholar Council) [2009631048]
- NSFC [20921120405, 21021002, 20828005]
- DOE [DE-FG02-07ER15895]
- NSF [CHE-0923910]
- Division Of Chemistry [0923910] Funding Source: National Science Foundation
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Unexpected yet highly remarkable and intriguing observations of the polymer-enhanced electro-catalytic activity of the Pt nanoparticles for electro-oxidations of both methanol and formic acid were reported. In situ FTIR investigation suggests strongly that the observed activity enhancements are highly likely due to the PVP-induced additional reaction pathways. These observations may open up a new paradigm of research in which the protecting/stabilizing organic ligands can now be incorporated as an advantageous part and/or a finer catalytic activity tuner of a nanocatalytic system.
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