Journal
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 12, Issue 23, Pages 6226-6232Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/c001438a
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Funding
- EPSRC [EP/D073472/1]
- Engineering and Physical Sciences Research Council [EP/D073472/1] Funding Source: researchfish
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The photoelectron spectrum of the 7,7,8,8- tetracyanoquinodimethane (TCNQ) radical anion has been measured at 3.1 eV. Additionally, the ultrafast relaxation dynamics of the first excited state (1(2)B(3u)) of TCNQ(-) have been studied using time-resolved photoelectron spectroscopy, which reveals that it undergoes internal conversion back to the ground state ((2)B(2g)) with an associated lifetime of 650 fs and shows evidence of coherent nuclear motion.
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