4.6 Article

Response of the potential of a gold electrode to elastic strain

Journal

PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 11, Issue 40, Pages 9008-9012

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b913448d

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Funding

  1. DFG [WE 1424/13]

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We describe the measurement of the response, 1, of the potential of a metal electrode to elastic strain under open circuit conditions. The experimental response exhibits a frequency dependence due to Faraday loss currents, which become negligible beyond 30 Hz. For a (111)-textured gold film the experimental value at higher frequency, zeta = -1.83 V, compares well with the intrinsic value of Au(111) predicted by recent ab initio computation.

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