4.6 Article

Large two-photon absorption cross section: molecular tweezer as a new promising class of compounds for nonlinear optics

Journal

PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 11, Issue 15, Pages 2592-2596

Publisher

ROYAL SOC CHEMISTRY
DOI: 10.1039/b822395e

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Funding

  1. Norwegian Research Council [179568/V30]
  2. YFF [162746, V00]
  3. Norwegian Supercomputing Program

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We report the highest two-photon absorption cross-section to date, obtained for a molecular tweezer complex. Our analysis suggests that long-range charge-transfer interaction in three dimensions is the main source of this very large two-photon absorption cross section.

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