Journal
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 10, Issue 48, Pages 7257-7261Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b811010g
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Funding
- EU [NMP4-CT-2006-032109]
- Spanish MEC [MAT2004-20291-E, MAT2007-62732]
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Metal-organic frameworks (MOFs) selectively grown on COOH-functionalized surfaces have been investigated by scanning force microscopy. Thickness and surface roughness analysis reveals that the use of a novel protocol based on a layer-by-layer approach results in a controlled growth yielding extremely homogeneous and preferentially oriented materials. The results are described within a sequential growth model and turn out to be promising for building up MOF-based 3D architectures of high quality.
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