Journal
PHYSICAL CHEMISTRY CHEMICAL PHYSICS
Volume 10, Issue 17, Pages 2356-2367Publisher
ROYAL SOC CHEMISTRY
DOI: 10.1039/b719618k
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The use of an O-18/O-16 exchange experiment as a means for probing surface space-charge layers in oxides is examined theoretically and experimentally. On the basis of a theoretical treatment, isotope penetration profiles are calculated for O-18/O-16 exchange across a gas-solid interface and subsequent diffusion of the labelled isotope through an equilibrium space-charge layer depleted of mobile oxygen vacancies and into a homogeneous bulk phase. Profiles calculated for a range of conditions all have a characteristic shape: a sharp drop in isotope fraction close to the surface followed by a normal bulk diffusion profile. Experimental O-18 profiles in an exchanged (001) oriented single crystal of Fe-doped SrTiO3 were measured by time-of-flight secondary ion mass spectrometry (ToF-SIMS). By extracting the space-charge potential from such profiles, we demonstrate that this method allows the spatially resolved characterization of space-charge layers at the surfaces of crystalline oxides under thermodynamically well-defined conditions.
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