Journal
PHYSICA STATUS SOLIDI-RAPID RESEARCH LETTERS
Volume 8, Issue 2, Pages 191-193Publisher
WILEY-V C H VERLAG GMBH
DOI: 10.1002/pssr.201308256
Keywords
dielectric properties; conductivity; spin crossover; thermal hysteresis
Funding
- joint French-Romanian project ANR-UEFISCDI [9RO-FR/01.02.2013, ANR-12-IS07-0003-01]
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Spin crossover compounds are considered to be a viable alternative for creating display, memory and switching devices due to the bistability of their magnetic, optical, mechanical and electrical properties. This Letter presents the study of the dielectric and transport properties of the [Fe(Htrz)(2)(trz)](BF4) (Htrz = 1H-1,2,4-triazole) complex in a wide temperature and frequency range. Our results reveal a singular behavior of the dielectric modulus upon the spin transition in conjunction with the switching of the conductivity between the high spin and low spin states. [GRAPHICS] ((c) 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim)
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