4.5 Article

High-pressure high-temperature synthesis of Rh2O3-II-type In2O3 polymorph

Journal

PHYSICA STATUS SOLIDI-RAPID RESEARCH LETTERS
Volume 2, Issue 6, Pages 269-271

Publisher

WILEY-V C H VERLAG GMBH
DOI: 10.1002/pssr.200802201

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Funding

  1. ESRF [HS-3413]
  2. [DFG-SPP 1236]

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The metastability of the bixbyite- and corundum-type In2O3 polymorphs up to 33 GPa (at room temperature). is shown. While compressed (in diamond anvil cells) and laser-heated, both polymorphs undergo a phase transition to the Rh2O3-II-type structure (space group Pbcn, No. 60). The direct transition from bixbyite to Rh2O3-II structure has not yet been observed for any other oxide.

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