Journal
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
Volume 186, Issue 2, Pages 271-280Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/10426507.2010.494919
Keywords
Chemoselective; oxidation; sulfides; sulfoxides; urea hydrogen peroxide (UHP); uronium hydrogen sulfate (UHS)
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Funding
- Persian Gulf University, Bushehr, Iran
- Hamedan University of Medical Sciences
- Center of Excellence of Development of Chemical Methods, (CEDCM), Bu-Ali Sina University, Hamedan, Iran
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An efficient, chemoselective, and metal-free oxidation of sulfides is described using urea-hydrogen proxide (UHP) adduct as a stable, inexpensive, and easily handled reagent in the presence of uronium hydrogen sulfate (UHS). Both UHP and UHS release urea as an environmentally benign byproduct. The advantages of the described method are generality, chemoselectivity, short reaction time, low cost, high atom economy, and green chemistry protocols.
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