Journal
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
Volume 185, Issue 1, Pages 193-203Publisher
TAYLOR & FRANCIS LTD
DOI: 10.1080/10426500902758386
Keywords
Disulfides; homoselective oxidation; melamine hydrogen peroxide; sulfoxides; transition metal-free oxidation
Categories
Funding
- Management and Programming Organization of I. R. Iran
- Center of Excellence in Development of Chemical Methods (CEDCM), Bu-Ali Sina University, Hamedan, Iran
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Melamine hydrogen peroxide (MHP) as a novel hydrogen peroxide adduct was easily prepared. Both chemo- and homoselective oxidation of thiols and sulfides to their corresponding disulfides and sulfoxides occurred by using MHP in moderate to excellent yields. AlCl3 acts as a suitable activator in the oxidation of sulfides with MHP.
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