4.1 Article

Application of BU4N+HSO4- as an ionic liquid and acid catalyst for thioacetalization of aldehydes and ketones

Journal

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
Volume 183, Issue 10, Pages 2502-2508

Publisher

TAYLOR & FRANCIS LTD
DOI: 10.1080/10426500801967757

Keywords

acid catalyst; carbonyl compound; ionic liquid; thioacetalization

Funding

  1. Isfahan University of Technology (IUT)
  2. National Institutes of Health, USA [GM 033138, MH 065503, NS 033650]
  3. Center of Excellency in Chemistry Research

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A variety of carbonyl containing compounds have been successfully reacted with 1,2-ethanedithiol in a thioacetylization reaction using tetrabutylammonium hydrogensulfate as a mild and efficient catalyst. Aldehydes and ketones react with good to excellent yields under mild conditions.

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