Journal
TURKISH JOURNAL OF CHEMISTRY
Volume 39, Issue 6, Pages 1180-1189Publisher
Tubitak Scientific & Technological Research Council Turkey
DOI: 10.3906/kim-1505-117
Keywords
Sonogashira reaction; anthracene; pentacene; organic field-effect transistors
Funding
- University of Strasbourg
- CNRS
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Five dissymmetrically functionalized anthracene analogues (3a-e) were synthesized from commercially available 9,10-dibromoanthracene through an efficient bromine iodine exchange followed by two successive Sonogashira coupling reactions. The resulting TMS-anthracene analogues are interesting building blocks for the preparation of highly pi-conjugated dissymmetric pentacene-based dyads, which could be used as active semiconducting layers for organic field-effect transistors (OFETs).
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