Palaeosalinity variations in the Early Cretaceous of the Neuquen Basin, Argentina: Evidence from oxygen isotopes and palaeoecological analysis

The Neuquen Basin is a stratigraphically- and economically-important Early Cretaceous depocentre located in west-central Argentina. The Early Valanginian to Early Barremian succession (upper Vaca Muerta, Mulichinco and Agrio Formations) contains a rich fossil record, with abundant bivalves and ammonoids. Palaeosalinities are determined systematically throughout the succession, based on an oxygen isotope analysis of unaltered oyster shells from two localities in Neuquen province. A total of 188 oyster samples from 52 stratigraphic levels were processed. A total of 52 mean values of delta O-18 isotope are used to calculate palaeosalinities, assuming an estimated water temperature of 25 degrees C. The observed range of palaeosalinities, between the maximum and the minimum, is 19, which is in conflict with published accounts of this being a fully marine succession. The isotopic data are combined with independent faunal evidence to evaluate palaeosalinity variation both laterally and temporally. Significant fluctuations in water salinity are indicated, with a clear tendency to increase from brachyhaline to euhaline and near hyperhaline conditions through time. The fluctuations were probably due to dilution from normal marine water, caused primarily by variations in rainfall and continental runoff. In addition, the presence of a volcanic island arc along the western margin of the basin may have at least partially isolated the basin from the marine waters of the Pacific Ocean. Also, a gulf-shaped basin may have inhibited hydrodynamic exchange with the ocean while enhancing retention of continental waters. (C) 2008 Elsevier B.V. All rights reserved.