Journal
TRAC-TRENDS IN ANALYTICAL CHEMISTRY
Volume 65, Issue -, Pages 22-29Publisher
ELSEVIER SCI LTD
DOI: 10.1016/j.trac.2014.10.009
Keywords
Cationic cyclodextrin; Chiral additive; Chiral recognition; Chiral separation; Complexation; Enantioselectivity; Mobile phase; Monocationic cyclodextrin; Polycationic cyclodextrin; Stationary phase
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Funding
- National Natural Science Foundation of China [21305066]
- Program for New Century Excellent Talents in University [NCET-12-0633]
- Ministry of Education of China [20103219120008]
- Jiangsu Province Natural Science Fund for Distinguished Young Scholars [BK20130032]
- Fundamental Research Funds for the Central Universities [30920130111006]
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Cationic cyclodextrins (CDs) have attracted considerable interest in the field of chiral separation. Targeting effective modulation of the interactions between chiral selectors and analytes for enhanced chiral recognition, a growing library of positively charged CDs has been developed for different analytical techniques. This review updates the research endeavors of synthetic and analytical chemists in evaluating enantioselectivity of cationic CDs using different analytical methods and the study of the chiral recognition mechanism. We pay specific attention to the structurally defined cationic CDs, which have been explored for versatile chiral separation in a variety of techniques when subject to further modification. (C) 2014 Elsevier B.V. All rights reserved.
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