Journal
ORGANOMETALLICS
Volume 33, Issue 21, Pages 5940-5943Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om500847j
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Funding
- EPSRC from the Bristol Chemical Synthesis Centre
- EPSRC [EP/K012258/1, EP/K013505/1, EP/K03927X/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [EP/K012258/1, EP/K013505/1, EP/K03927X/1] Funding Source: researchfish
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Activation of B(2)pin(2) with (BuLi)-Bu-t facilitates the Fe-catalyzed borylation of alkyl, allyl, benzyl, and aryl halides via the formation of Li[B(2)pin(2)(Bu-t)] (1). The reaction of 1 with a representative iron phosphine precatalyst generates the unique iron(I) boryl complex [Fe(Bpin)(dpbz)(2)] (2).
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