Journal
ORGANOMETALLICS
Volume 33, Issue 11, Pages 2831-2836Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om5003528
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- Ministry of Science and Technology [NSC100-2113-M-002-001-MY3]
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The synthesis of water-soluble (eta(6)-arene)ruthenium(II) complexes based on pyrazolyl naphthyridine ligands modified with a carboxylate group is reported. The complexes are easily accessible in good yields via complexation of [(arene)RuCl2](2) with 7-pyrazolyl-1,8-naphthyridine-2-carboxylic acid (1). All complexes have been characterized by spectroscopic and elemental analyses. The complexes {[Ru(eta(6)-arene)(N,N'-1)Cl]Cl} (arene = benzene (5), p-cymene (6)) were further confirmed by X-ray diffraction studies. These complexes are soluble in water (ca. 10 mg/mL) and are catalytically active in hydrogen-transfer reduction of carbonyl compounds in aqueous medium with the use of HCOOH/HCOONa as the hydrogen source.
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