Journal
ORGANOMETALLICS
Volume 33, Issue 9, Pages 2247-2256Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om5001293
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Funding
- National Research Foundation (NRF)
- DST-NRF Centre of Excellence in Catalysis (c*change)
- Erasmus Mundus EUROSA program
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A series of novel neutral and cationic methylpalladium complexes bearing N-alkyl-2,2'-dipyridylaldiminato ligands were prepared and characterized. In the presence of ethylene, the cationic complexes were active as dimerization catalysts, producing a mixture of 1- and 2-butenes. A Pd-ethyl pi-ethylene species was identified as the catalyst resting state by low-temperature spectroscopic and DFT studies, which provided insights into the effect of both steric and electronic factors on the observed reactivity.
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