Journal
ORGANOMETALLICS
Volume 33, Issue 22, Pages 6704-6707Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om500957a
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- Ministry of Education, Culture, Sports, Science and Technology, Japan
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Palladium-catalyzed regioselective homocoupling of arylpyridines under anodic oxidation conditions was achieved in the presence of I-2. The dimerization of meta-substituted arylpyridines proceeded selectively at less-sterically congested ortho-positions, and the selectivity is different from that reported for the palladium-catalyzed dimerization using Oxone as an oxidant. The dimerization also proceeds using catalytic amounts of both Pd(OAc)(2) and I-2 under the electrochemical reaction conditions.
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