Journal
ORGANOMETALLICS
Volume 33, Issue 24, Pages 7241-7246Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om501033p
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Funding
- Royal Society
- University of Manchester
- EPSRC [EP/K039547/1]
- EPSRC [EP/K039547/1] Funding Source: UKRI
- Engineering and Physical Sciences Research Council [1232343, EP/K039547/1] Funding Source: researchfish
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The dehydrosilylation of 2-(SiR2H)-biphenyls catalyzed by B(C6F5)(3) and a weak base forms silafluorenes with H-2 as the only byproduct. Attempts to extend this approach to synthesize siloles derived from 2,2'-bithiophenes and N-Me-2-Ph-indole resulted in competing reactivity, including protodesilylation. B(C6F5)(3) also catalyzed the one-pot, two-step formation of silaindenes from aryl-alkynes by alkyne trans-hydrosilylation, followed by an intramolecular Sila-Friedel-Crafts reaction facilitated by a weak base.
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