Journal
ORGANOMETALLICS
Volume 33, Issue 14, Pages 3695-3701Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om500212x
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- NSERC Discovery Program
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The first instances of ruthenium alkylidene complexes based on chelating phosphine sulfonates are presented. Although these complexes are formally 18-electron complexes bearing cis phosphines and cis one-electron donors (sulfonates and chlorides), they are surprisingly active for ring-closing metathesis, cross-metathesis, and ring-opening metathesis polymerization, thus highlighting the unique potential of the sulfonate ligand in the design of a ruthenium metathesis catalyst.
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