Journal
ORGANOMETALLICS
Volume 33, Issue 7, Pages 1665-1671Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om500003d
Keywords
-
Categories
Funding
- DST New Delhi [SB/S1/OC-72/2013]
- CSIR of India
Ask authors/readers for more resources
An unusual trinuclear cobalt complex was successfully isolated and characterized in the Co(OAc)(2)center dot 4H(2)O-catalyzed aerobic oxidation of pyridine-based secondary alcohols. In this complex, a cobalt ion (the one in the middle, labeled Co-2) has a novel trigonal-prismatic structure coordinated with six oxygen atoms from the substrate. The molecular oxygen present in air plays a major role in enabling this transformation to be catalytic. This aerobic catalytic reaction is very selective to pyridine-based secondary alcohols over primary alcohols.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available