Journal
ORGANOMETALLICS
Volume 32, Issue 8, Pages 2459-2462Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om400175h
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Funding
- Funding Program for Next Generation World-Leading Researchers, Green Innovation from MEXT of Japan
- Global COE Program Chemistry Innovation through Cooperation of Science and Engineering from MEXT of Japan
- Grants-in-Aid for Scientific Research [24750089] Funding Source: KAKEN
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A copper/N-heterocyclic carbene catalyzed hydroboration of carbon dioxide has been developed to give a formic acid derivative selectively under mild conditions. Investigations directed toward understanding the catalytic cycle of this process have been carried out, and the hydroboration product can be directly used as a formylation reagent for various amines.
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