Journal
ORGANOMETALLICS
Volume 32, Issue 21, Pages 6587-6592Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om4008967
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Funding
- National Natural Science Foundation of China [21072030]
- Research Fund for the Doctoral Program of Higher Education of China [20123514110003]
- SRF for ROCS, SEM [J20121707]
- Science Foundation of the Fujian Province, China [2013J01040]
- Fuzhou University [022318, 022494]
- King Abdullah University of Science and Technology
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Copper(I) fluoride complexes ligated by phenanthroline derivatives have been synthesized and structurally characterized by X-ray crystallography. These complexes adopt as either ionic or neutral forms in the solid state, depending on the steric bulkiness of the substituent groups on the phenanthroline ligands. These complexes react with primary and secondary alkyl bromides to produce the corresponding alkyl fluorides in modest to good yields. This new method is compatible with a variety of important functional groups such as ether, thioether, amide, nitrile, methoxyl, hydroxyl, ketone, ester, and heterocycle moieties.
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