Journal
ORGANOMETALLICS
Volume 32, Issue 9, Pages 2674-2684Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om400152x
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- EPSRC
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Isomeric diborylated ferrocenes featuring 1,1'-, 1,2-, and 1,3-substitution patterns have been targeted via a combination of electrophilic aromatic substitution and directed ortho-lithiation protocols. While none of these systems are competent for the Lewis acid chelation of fluoride, related systems featuring a mixed B/Si acceptor set capture 1 equiv of fluoride via a Si-F-B bridging motif.
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