Journal
ORGANOMETALLICS
Volume 32, Issue 6, Pages 1958-1963Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om400046r
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Funding
- NSFC [21072149, 20872108]
- Innovation Foundation of Tianjin University
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A series of aryl-substituted pyrrole derivatives was synthesized from diallylamines through a ruthenium carbene catalyzed ring-closing metathesis reaction and in situ oxidative dehydrogenation reaction catalyzed by FeCl3 center dot 6H(2)O or CuCl2 center dot 2H(2)O in the presence of O-2. The reaction was mild, simple, and convenient. An oxygen atmosphere played a critical role in obtaining high conversion of substituted pyrroles in the proposed catalytic system.
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