Journal
ORGANOMETALLICS
Volume 31, Issue 22, Pages 7816-7818Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om300393m
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Funding
- Welch Foundation [E-1571]
- NIGMS [R01GM077635]
- Norman Hackerman Advanced Research Program
- Camille and Henry Dreyfus Foundation
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A method for copper-catalyzed oxidative dimerization of nitronates and enolates using oxygen as the terminal oxidant has been developed. Cyclization through oxidative intramolecular coupling is also feasible for both nitronates and enolates. The mild reaction conditions lead to good functional group tolerance.
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