Journal
ORGANOMETALLICS
Volume 31, Issue 14, Pages 5208-5211Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om300422v
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- King Abdullah University of Science and Technology
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Dehydrogenative homocoupling of primary alcohols to form esters and coupling of amines to form imines was accomplished using a class of novel pincer ruthenium complexes. The reactivities of the ruthenium pincer complexes for the direct coupling of amines to form imines were enhanced by introducing an imine arm to the pincer ligand. Selective oxidation of benzylamines to imines was achieved using aniline derivatives as the substrate and solvent.
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