Journal
ORGANOMETALLICS
Volume 31, Issue 8, Pages 2949-2952Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om300127g
Keywords
-
Categories
Funding
- NSERC of Canada
- Canada Council of the Arts
- NSERC
- Alberta Innovates-Technology Futures
Ask authors/readers for more resources
The synthesis of two members of a new PCP pincer ligand family and their complexation with iridium has been developed. Double C-H activation results in a ligand anchored by a carbene donor; hydrogen reversibly adds to the (PCcarbeneP)-IrCl complexes 3(R) (R = Pr-i, Bu-t). Aryl, amido, and phenoxy derivatives are available from the chlorides via salt metathesis. These compounds add H-2 and eliminate H-X; the iridium compound is trapped as a PCalkylP iridium polyhydride.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available