Journal
ORGANOMETALLICS
Volume 31, Issue 8, Pages 3355-3360Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om300148q
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Funding
- Spanish Ministerio de Ciencia e Innovacion [CTQ2008-02918/BQU, CTQ2011-24096]
- Ministerio de Educacion
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The synthesis and characterization of new water-soluble platinum(0) complexes bearing sulfonated N-heterocyclic carbene (NHC) and divinyltetramethylsiloxane (dvtms) ligands are described. These complexes, of the general formula (NHC)Pt(dvtms), are active and recydable catalysts for the hydrosilylation of phenylacetylene and other alkynes at room temperature in water. Our findings indicate that the NHC-Pt(0) bonds are reasonably stable under these catalytic conditions, although hydrolysis is observed at temperatures above 80 degrees C in pure water.
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