Journal
ORGANOMETALLICS
Volume 31, Issue 21, Pages 7320-7323Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om3008162
Keywords
-
Categories
Funding
- CNRS
- French Ministry for Research
- institut Universitaire de France
- ANR [09-Blanc-0101-01]
- DST India
Ask authors/readers for more resources
The alkenylation with alkyl acrylates of ferrocenyl alkyl ketones is performed with the [RuCl2(p-cymene)](2)/AgSbF6 catalytic system and leads, via ferrocene C-H bond activation, to moderate yields of the 1,2-disubstituted ferrocene derivatives in the presence of Cu(OAc)(2)center dot H2O under aerobic conditions at 80-110 degrees C. The alkenylation of ferrocenyl phenyl ketone, in contrast, takes place at room temperature to afford quantitative yields of the phenyl monoalkenylated product, demonstrating the strong influence of the ferrocenyl group on arene C-H bond functionalization. Small amounts of 2-alkenylferrocenyl 2'-phenyl ketones can also be obtained.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available