Journal
ORGANOMETALLICS
Volume 31, Issue 18, Pages 6518-6521Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om300722g
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Funding
- National Basic Research Program of China (973 Program) [2011CB808705]
- National Natural Science Foundation of China [20872168, 21002114, 21121062]
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Iron-catalyzed cross-coupling of nonactivated primary alkyl fluorides with aryl Grignard reagents has been achieved by using the low-coordinate dinuclear iron complex [(IPr2Me2)Fe(mu(2)-NDipp)(2)Fe(IPr2Me2)] as the catalyst. This iron-catalyzed C(sp(3))-F bond arylation reaction is applicable to a variety of aryl Grignard reagents and primary alkyl fluorides. The product pattern suggests the involvement of a radical-type mechanism for its C-F bond scission step.
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