Journal
ORGANOMETALLICS
Volume 31, Issue 23, Pages 8437-8443Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om301046t
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Funding
- Funding Program for Next Generation World-Leading Researchers [GR025]
- MEXT, Japan
- Toyota Motor Corporation
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Novel dinitrogen-bridged dimolybdenum complexes bearing unsymmetric PNP-type pincer ligands are prepared and characterized by X-ray analysis. A molybdenum-dinitrogen complex bearing 2-(di-1-adamantylphosphino)methyl-6-(di-tert-butylphosphino)methylpyridine has been found to work as an effective catalyst toward the formation of ammonia from molecular dinitrogen under ambient conditions.
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