Journal
ORGANOMETALLICS
Volume 31, Issue 2, Pages 768-771Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om200948z
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Funding
- NSF [CHE-0555425]
- NCBC [2008-IDG-1010]
- Duke University
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The dicationic bis(gold)-biarylphosphine pi-alkene complexes {(P-P)[Au(pi-alkene)](2)}(2+)2SbF(6)(-) [P-P = 2,2'-bis(di-tert-butylphosphino)biphenyl; alkene = isobutylene, 1-pentene] were isolated in >95% yield from reaction of alkene with a 1:2 mixture of (P-P)(AuCl)(2) and AgSbF6 and were characterized by NMR spectroscopy and X-ray crystallography.
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