Journal
ORGANOMETALLICS
Volume 30, Issue 3, Pages 372-374Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om100981v
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Funding
- European Research Council (ERC) [202886-CatCIR]
- NWO-CW [700.55.426, 700.59.410]
- MEC/FEDER (Spain) [CTQ2008-03860]
- University of Amsterdam
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The binuclear iridium complex [(cod)(Cl)Ir(bpi)Ir(cod)]PF6(bpi = (pyridin-2-ylmethyl)(pyridin-2-ylmethylene)amine; cod = 1,5-cyclooctadiene) reveals a noteworthy asymmetric binuclear coordination geometry, wherein the bpi ligand acts as a heteroditopic ligand and has an unusual pi-coordinated imine moiety. This species is an effective precatalyst for water oxidation. After a short incubation time the catalyst reveals a turnover frequency of 3400 mol mol(-1) s(-1) with an overall turnover number > 1000.
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