Journal
ORGANOMETALLICS
Volume 30, Issue 5, Pages 1162-1167Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om101145y
Keywords
-
Categories
Funding
- MCINN of Spain [CTQ2008-04460]
- Bancaixa [P1.1B2007-04]
- European Research Council [StG 208561]
- MICINN
Ask authors/readers for more resources
A series of Ru-II(eta(6)-arene) complexes with 1,2,3-triazolylidene ligands have been prepared and fully characterized. The molecular structure of one of the new complexes has been determined by means of X-ray diffractrometry. The new complexes have been tested in a set of catalytic reactions involving alcohols and amines as substrates, including (i) base-free oxidation of benzylic alcohols to benzaldehydes, (ii) homocoupling of amines to form imines, and (iii) oxidative coupling of amines and alcohols to form amides. The results show the high versatility of the catalysts used and illustrate the application potential of 1,2,3-triazolylidene ligands in the design of effective homogeneous catalysts.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available