Journal
ORGANOMETALLICS
Volume 30, Issue 8, Pages 2418-2424Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om200154a
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Funding
- MOST [2009AA033601]
- EPSRC [EP/H031855/1]
- Engineering and Physical Sciences Research Council [EP/H031855/1] Funding Source: researchfish
- EPSRC [EP/H031855/1] Funding Source: UKRI
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A series of 2,6-dibenzhydryl-N-(2-phenyliminoacenaphthylenylidene)-4-methylbenzenamines (L1-L5) and the nickel(II) dibromide complexes thereof (C1-C5) were synthesized and. fully characterized. The molecular structures of representative complexes were determined by single-crystal X-ray diffraction and revealed a distorted-pyramidal geometry at nickel. All nickel(II) pro catalysts exhibited very high activity for the polymerization of ethylene, with activities as high as the range of 10(7) g of PE (mol of Ni)(-1) h(-1)
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