Journal
ORGANOMETALLICS
Volume 30, Issue 22, Pages 6323-6327Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om200945q
Keywords
-
Categories
Funding
- Ministry of Education, Culture, Sports, Science and Technology, Japan [B01]
- Grants-in-Aid for Scientific Research [22550092] Funding Source: KAKEN
Ask authors/readers for more resources
Palladium/(4-MeO-3,5-MePh)(2)PF-Pcy(2)) catalyzed the enantioselective arylation of silyl ketene acetals with iodoarenes in the presence of TlOAc to promote transmetalation of silyl ketene acetals. The highest enantioselectivities giving alpha-arylesters up to 91% ee were achieved when (E)-1-methoxy-1-(trimethylsiloxy)propene (E/Z = 88/12) was used for the silyl ketene acetal. The effect on enantioselection of a chiral ligand is discussed on the basis of the X-ray structure of the palladium/(4-MeO-3,5-MePh)(2)PF-Pcy(2)) complex and results of DFT computational studies on mechanistic aspects of the catalytic cycle.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available