Journal
ORGANOMETALLICS
Volume 30, Issue 13, Pages 3479-3482Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om200437n
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- NSERC of Canada
- SHARC-NET facilities
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A series of pincer-type complexes of Os and Ru have been synthesized and investigated in catalytic alcohol dehydrogenation. The hydrides OsHCl(CO)[HN(C(2)H(4)PiPr(2))(2)] and OsH2-(CO)[HN(C(2)H(4)PiPr(2))(2)] possess good air, moisture, and thermal stability and are outstanding versatile dehydrogenation catalysts for primary alcohols for reactions of transfer hydrogenation, dehydrogenative coupling, and amine alkylation.
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