Electronically Intercommunicating Iron Centers in Di- and Tetraferrocenyl Pyrroles

Novel 2,5-diferrocenyl-1-phenyl-1H-pyrrole (4) and 2,3,4,5-tetraferrocenyl-1-phenyl-1H-pyrrole (6) have been prepared by a 2- or 4-fold Negishi cross-coupling reaction of 2,5-dibromo-1-phenyl-1H-pyrrole (3) and 2,3,4,5-tetrabromo-1-phenyl-1H-pyrrole (5), respectively, with FcZnCl (2) (Fc = Fe(eta(5)-C5H4)(eta(5)-C5H5)) in the presence of [(Ph3P)(4)Pd] as catalyst. The electronic and structural properties of 4 and 6 were investigated with UV-vis spectroscopy and single-crystal X-ray diffraction (6). Comparison of the appropriate bond distances in the pyrrole core system of 6 demonstrates considerable electron delocalization. Cyclic, square wave, and linear sweep voltammetry as well as in situ MR spectro-electrochemistry highlight the electrochemical properties of both compounds. Molecules 4 and 6 display two (4) or four (6) electrochemically reversible one-electron transfer processes with remarkably high Delta E-1/2 values and reduction potentials of E-0t = -238 and E-0t = 212 mV for 4 (Delta E-1/2 = 450 mV) and E-0t = 280, E-0t = 51, E-0t = 323, and E-0t = 550 mV for 6 (Delta E-1/2 = 322, 2154, and 233 mV) using [NBu4][B(C6F5)(4)] as the supporting electrolyte. The pyrroles could be classified as class II systems according to Robin and Day. Additionally, 4[PF6](n) (n = 1, 2) were synthesized and studied, giving CV responses and NIR spectra identical to those obtained for 4 from electrochemical oxidations.