Journal
ORGANOMETALLICS
Volume 31, Issue 1, Pages 35-38Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om200910p
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- CNRS
- Ministere de la Recherche et de l'Enseignement Superieur
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A novel heteroleptic cyclometalated iridium(III) complex with one picolinic acid derivative bearing a pendant terminal alkynyl tether has been prepared following a new synthetic route. This pendant alkynyl tether can be further engaged in palladium C-C coupling reactions, allowing its grafting to a Keggin-type polyoxometalate and thus providing a unique iridio-POM conjugate.
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