Journal
ORGANOMETALLICS
Volume 30, Issue 21, Pages 6017-6021Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om200844b
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Funding
- NIH [R01 GM 68825]
- DOE [DE-FG02-09ER16069]
- FQRNT
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Direct metalation of bis(1,2,3-triazolium) salts affords mononuclear rhodium(I) complexes, which feature a 1,4-bidentate bis(1,2,3-triazol-5-ylidene) (i-bitz) ligand. The topology of the ligand is similar to that of 2,2'-bipyridines (bpy) and their congeners, as well as bis(1,2,4-triazol-5-ylidenes) (bitz). As the former, but in contrast to the latter, the free i-bitz can be isolated, which paves the way for various applications.
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