Journal
ORGANOMETALLICS
Volume 30, Issue 9, Pages 2468-2471Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om200290u
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Funding
- MICINN of Spain [CTQ2008-00810, CSD2007-00006]
- Diputacion General de Aragon [E35]
- European Social Fund
- Austrian Science Fund (FWF) [E35] Funding Source: Austrian Science Fund (FWF)
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An easy and direct access to POP-type osmium(II) and osmium(IV) complexes, including OsH(4){dbf(P(i)Pr(2))(2)} (dbf(P(i)Pr(2))(2) = bis(diisopropylphosphine)dibenzofuran), is reported. This tetrahydride derivative is an efficient catalyst for the selective formation of imines from alcohols and amines with liberation of H(2), proving that osmium is a promising alternative to ruthenium for catalysis.
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