Journal
ORGANOMETALLICS
Volume 30, Issue 13, Pages 3464-3467Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om200404p
Keywords
-
Categories
Funding
- Natural Science Foundation of China
- MOST of China [2011CB808705]
Ask authors/readers for more resources
The first well-defined zirconocene complexes processing vinyl-imine and keteniminate species have been achieved from zirconacyclopentenes or zirconacyclopentadienes and 2 equiv of Ph2CHCN. Multifunctional effect of Ph2CHCN is observed for the first time in one system. This process proceeds via the azazirconacyclopentadiene intermediate and its intramolecular proton transfer. Moreover, beta,beta'-C-C bond cleavage of tetra-alkyl-substituted zirconacyclopentadienes is observed for the first time under the appropriate conditions.
Authors
I am an author on this paper
Click your name to claim this paper and add it to your profile.
Reviews
Recommended
No Data Available