Journal
ORGANOMETALLICS
Volume 30, Issue 4, Pages 657-660Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om1011769
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Funding
- Centre National de la Recherche Scientifique (CNRS)
- Universite Paul Sabatier (UPS)
- COST action (PhoSciNet) [CM0802]
- Agence Nationale de la Recherche Scientifique [ANR-10-BLAN-070901]
- CAlmip (Toulouse)
- CINES (Montpellier)
- GEN-CI (Grand Equipement National de Calcul Intensif) [i2010080045]
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The triphosphine-indane TPI([o-i-Pr2P(C6H4)](3)In) has been prepared and found to react with [Pd(P-t-Bu-3)(2)] and [AuCl(SMe2)]. According to X-ray diffraction analyses and DFT calculations, the ensuing complexes both display original donor acceptor M In interactions, although of markedly different nature and magnitude.
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