4.5 Article

Ruthenium Hydroxide Complexes in the Racemization of Secondary Alcohols

Journal

ORGANOMETALLICS
Volume 30, Issue 23, Pages 6347-6350

Publisher

AMER CHEMICAL SOC
DOI: 10.1021/om200956r

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Funding

  1. ERC
  2. Royal Society

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Two well-defined 16-electron ruthenium hydroxide complexes were prepared and successfully used in the racemization of aromatic and aliphatic secondary alcohols. The intrinsic basicity of these new complexes permits for the exclusion of KO'Bu in the racemization reaction.

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