Journal
ORGANOMETALLICS
Volume 30, Issue 8, Pages 2241-2251Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om2000426
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Funding
- Centre National de la Recherche Scientifique (CNRS)
- Ministere de la Recherche
- Fundacao para a Ciencia e Tecnologia (FCT) [SFRH/BPD/44262/2008]
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A series of cationic gold(I) alpha-diimine complexes of the type [(NHC)Au(alpha-diimine)]X or [(PPh3)Au(alpha-diimine)]X, where NHC = IPr, alpha-diimine = BIAN-dipp, X = PF6 (1); X = BF4 (2); X = SbF6 (3); NHC = (IBu)-Bu-t, alpha-diimine = BIAN-dipp X = PF6 (4); X = BF4 (5); NHC = IMes, alpha-diimine = BIAN-dipp, X = PF6 (6); PPh3, alpha-diimine = BIAN-dipp, X = PF6 (7); NHC = IPr, alpha-diimine = DAB-Mes, X = PF6 (8, 10) bearing an N-heterocyclic carbene (NHC) or a phosphine ligand, have been synthesized and characterized by NMR spectroscopy and single crystal X-ray diffraction. The stability of the new complexes and their catalytic activity for the intermolecular addition of the indole nucleophilic carbon to 1,6-enyne were also investigated.
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