Journal
ORGANOMETALLICS
Volume 29, Issue 10, Pages 2199-2202Publisher
AMER CHEMICAL SOC
DOI: 10.1021/om100060y
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- KAUST (King Abdullah University of Science and Technology)
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The nickel-induced coupling of ethylene and CO2 represents a promising pathway toward acrylates. To overcome the high bond dissociation energies of the M-O moieties, we worked out an in situ methylation of nickelalactones to realize the beta-hydirde elimination and the liberation of the acrylate species.
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